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The quality of the water used in emulsion polymerization is important. Deionized water may be used since the presence of foreign ions or ions in uncontrolled concentrations can interfere with both the initiation process and the action of the emulsi er. Antifreeze additives are used to allow polymerization at temperatures below 0 C. These include inorganic electrolytes as well as organics such as ethylene glycol, glycerol, methanol, and monoalkyl ethers of ethylene glycol. The addition of inorganic electrolytes often affects the polymerization rate and stability of the emulsion. Sequestering agents such as ethylenediamine tetraacetic acid or its alkali metal salts may be added to help solubilize a component of the initiator system or to deactivate traces of calcium and magnesium ions present in the water. Buffers such as phosphate or citrate salts may be used to stabilize the latex toward pH changes. 4-3d Propagation and Termination Rate Constants

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void ISupportInitializeBeginInit() { m_Initializing = true; }

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Emulsion polymerization proceeds in a polymer particle where the concentration of polymer is quite high throughout the reaction. This type of system is similar to a bulk polymerization in the later stages of reaction where there is a strong Trommsdorff effect. The propagation rate constant for an emulsion polymerization can be obtained for case 2 systems from the polymerization rate using Eq. 4-5, where " 0:5. One can ascertain that case 2 behavior n is present by observing whether the polymerization rate in interval II is insensitive to changes in the initiation rate. The value of kp can also be obtained from the degree of polymerization using Eq. 4-7. This is often a more reliable measure of kp since there is no need to make any assumption on the value of ". The propagation rate constant is generally found to have the n same value in emulsion polymerization as in the corresponding bulk polymerization at high conversion more speci cally, at a conversion corresponding to the volume fraction of polymer in monomer that exists in the emulsion system.

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The heat of an emulsion polymerization is the same as that for the corresponding bulk or solution polymerization, since H is essentially the enthalpy change of the propagation step Thus, the heats of emulsion polymerization for acrylic acid, methyl acrylate, and methyl methacrylate are 67, 77, and 58 kJ mol 1 , respectively [McCurdy and Laidler, 1964], in excellent agreement with the H values for the corresponding homogeneous polymerizations (Table 3-14) The effect of temperature on the rate of emulsion polymerization, although not extensively studied, is generally similar to that on homogeneous polymerization with a few modi cations The overall rate of polymerization increases with an increase in temperature Temperature increases the rate by increasing both kp and N The increase in N is due to the increased rate of radical generation at higher temperatures.

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void ISupportInitializeEndInit() { m_Data = m_TempData; m_Initializing = false; } }

Opposing this trend to a slight extent is the small decrease in the concentration of monomer in the particles at higher temperatures Thus, the value of [M] for styrene decreases $15% in going from 30 to 90 C [Smith and Ewart, 1948] The overall activation energy for emulsion polymerization is, thus, a combination of the activation energies for propagation, radical production, and [M] For the few systems studied, the overall activation energies for emulsion polymerization are approximately the same as or less than those for the corresponding homogeneous polymerization [Stavrova et al, 1965] Carrying out an emulsion polymerization requires an awareness of the krafft point of an ionic surfactant and the cloud point of a nonionic surfactant Micelles are formed only at temperatures above the Krafft point of an ionic surfactant For a nonionic surfactant, micelles are formed only at temperatures below the cloud point.

Emulsion polymerization is carried out below the cloud temperature of a nonionic surfactant and above the Krafft temperature of an ionic surfactant..

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