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Panico, R., W. H. Powell, and J.-C. Richer, eds., A Guide to IUPAC Nomenclature of Organic Compounds, Blackwell Scienti c, Oxford, 1993. Porter, R. S. and L. H. Wang, Rev. Macromol. Chem. Phys., C35(1), 63 (1995). Potschka, M. and P. L. Dublin, eds., Strategies in Size Exclusion Chromatography, American Chemical Society, Washington, D.C., 1996. Slade, P. E., ed., Polymer Molecular Weights, Springer, Berlin, 1998. Sperling, L. H., Introduction to Physical Polymer Science, 3rd ed., Wiley-Interscience, New York, 2001. Wendlandt, W. W., Thermal Analysis, 3rd ed., Wiley, New York, 1986. Wilks, E. S., Prog. Polym. Sci., 25, 9 (2000). Woodward, A. E., Atlas of Polymer Morphology, Hanser Verlag, Munich, 1989. Wunderlich, B., Macromolecular Physics, Vols. 1 3, Academic Press, New York, 1973. Yau, W. W., J. J. Kirkland, and D. D. Bly, Modern Size Exclusion Liquid Chromatography. Practice of Gel Permeation and Gel Filtration Chromatography, Wiley, New York, 1979.

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This document was created by an unregistered ChmMagic, please go to http://wwwbisentercom to register it Thanks Using a CustomersRow reference, you then get strongly typed access to each of the columns in the row based on the Name property you set for the column in the data set definition (as described earlier in the discussion about Figure 27) Both the CustomersDataTable and CustomersRow type definitions are nested classes within theCustomersDataSet class This means that to create a variable of that type in your code, you have to specify the outer class as well, in the form CustomersDataSetCustomersRow as seen in Listing 22 Beyond what is shown here, a lot more code is generated to support the public-facing members of the classes Each class has a lot of initialization code that runs at construction time; this code sets up the underlying schema of the data set to contain the expected data tables, columns, relations, constraints, and so on The initialization code also sets up some code to optimize the speed of accessing each individual column within the data set when accessed through the strongly typed properties I encourage you to spend some time browsing through the typed data set code to get a sense of what is defined in there The way you normally use typed data sets means that code is all just a black box to you, but it's a good idea to know how black boxes work if you really want to know how your program works and to be able to understand problems when your program doesn't work as expected It may also come in handy when you are misusing the black box, and the debugger stops on a line of code inside the data set definition code where things are blowing up

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PROBLEMS 1-1 Show by equations the overall chemical reactions involved in the synthesis of polymers from a. CH2 CH CO2H b.

h r1 ; r4 h r2 ; r3 h r1 ; r2 ; r3 ; r4 X h ri1 ; . . . ; rik h rj1 ; . . . ; rjm h rl1 ; . . . ; rln . . . hm r1 m r2 m rp i

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times as there is a greater tendency for capture of precursor particles by polymer particles when the latter concentrations are high Within the overall behavior predicted by Eq 4-11, there is compatibility with the 3-power dependence of N on Ri predicted by Eq 4-10 5 Nonpolar monomers such as styrene, with little tendency toward radical desorption, generally show 3- and 2-power dependencies of N on S and Ri , respectively This result, however, 5 5 cannot be taken to exclude coagulative nucleation since one cannot preclude the exponent of the dependence of N on S being larger and smaller, respectively, than 3 at lower and higher 5 concentrations of surfactant than those studied Monomers such as vinyl acetate and vinyl chloride, which show case 1 behavior, tend to show a dependence of N on S in line with that predicted by Eq 4-11, indicating the presence of coagulative nucleation.

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